Thursday, January 29, 2026

14.1 - Displacement of An Oscillating particle

In the previous section, we saw period and frequency. In this section, we will see displacement.

Let us first see the details of an oscillation. It can be written in 6 steps:
1. In fig.14.3 (a) below, a red block of mass m, is attached to a spring. The other end of the spring is fixed to a rigid wall. The block is resting on a friction-less surface.

Fig.14.3

2. In fig.14.3 (b), the block is pulled towards the right by a distance A. From this position, the block is released from rest. It will then travel towards the left. Even after traveling a distance 'A', it will continue to travel towards the left. That is., even after passing the point x= 0, it will continue to travel towards the left. This is shown in fig.c.

3. But once the point x = 0 is passed, the block will begin to experience a resistive force. The block is able to overcome the resistive force, and reach up to x = −A. Once it reaches x=−A, it stops. That is., it's velocity becomes zero. This is shown in fig.d.

4. Then it starts the reverse journey. In the reverse journey, even after passing the point x=0, it will continue to travel towards the right. This is shown in fig.e.

5. But once the point x = 0 is passed, the block will begin to experience a resistive force. The block is able to overcome the resistive force, and reach up to x = A. Once it reaches x=A, it stops. That is., it's velocity becomes zero. This is shown in fig.f.

6. At this point, one cycle is complete. Then it again starts the journey towards left. This process continues giving rise to continuous oscillation.


Displacement

The above 6 steps give us a basic understanding about oscillation. Now we will derive an expression for displacement. It can be done in 9 steps:
1. We saw that, the red block is oscillating between x=A and x=−A. Let us mark those two points as P and Q respectively, on the x-axis. This is shown in fig.14.4 below:

Fig.14.4

• The coordinates of P and Q are (A,0) and (−A,0) respectively. So O is the equilibrium position of the block.

2. Draw the red circle with center at O and radius equal to A.
• The magenta sphere is performing uniform circular motion along the red circle.
• The angular velocity of the magenta sphere is $\small{\omega}$.
• That means, the angle subtended by the sphere, at O, in each second, is $\small{\omega}$.

3. Consider the instant when the magenta sphere is at M. At that instant, the line OM makes an angle $\small{\theta}$ with the x-axis.
• Drop the perpendicular MN from M, onto the x-axis.
• From the right triangle OMN, we get:
$\small{ON~=~ OM\,\cos \theta~=~A\,\cos\theta}$.

4. Now, ON is the horizontal displacement of the magenta sphere from the equilibrium position O. So we get a method to write the horizontal displacement of the magenta sphere from O.

◼ Let us check for other points. For that, we will try to write a general method which is applicable to all points.

(i) In fig.14.5(a) below, M is in the I quadrant.
    ♦ On OM, Mark M' such that, OM' = 1 unit.
    ♦ Drop the perpendicular M'N' onto the x-axis.

Fig.14.5

• OMN and OM'N' are similar triangles. So we can write:
$\small{\frac{OM}{OM'}~=~\frac{ON}{ON'}}$
$\small{\Rightarrow~ON~=~OM\left(\frac{ON'}{OM'} \right)}$   
$\small{\Rightarrow~ON~=~A \left(\frac{ON'}{OM'} \right)}$
• Length of ON' is same as the x-coordinate of M'.
• Since OM' = 1 unit, the point M' is on the unit circle, and so, the x-coordinate of M' is $\small{\cos \theta}$ (Details here)
• So we get:
$\small{\Rightarrow~ON~=~A \left(\frac{\cos \theta}{1} \right)~=~A\,\cos \theta}$

(ii) In fig.14.5(b) above, M is in the II quadrant.
    ♦ On OM, Mark M' such that, OM' = 1 unit.
    ♦ Drop the perpendicular M'N' onto the x-axis.
• OMN and OM'N' are similar triangles. So we can write:
$\small{\frac{OM}{OM'}~=~\frac{ON}{ON'}}$
$\small{\Rightarrow~ON~=~OM\left(\frac{ON'}{OM'} \right)}$   
$\small{\Rightarrow~ON~=~A \left(\frac{ON'}{OM'} \right)}$
• Length of ON' is same as the x-coordinate of M'.
• Since OM' = 1 unit, the point M' is on the unit circle, and so, the x-coordinate of M' is $\small{\cos \theta}$
• So we get:
$\small{\Rightarrow~ON~=~A \left(\frac{\cos \theta}{1} \right)~=~A\,\cos \theta}$
• Since M is in the II quadrant, $\small{\cos \theta}$ will be −ve. Indeed, N will have a −ve x-coordinate because it is on the −ve side of the x-axis.

(iii) In fig.14.5(c) above, M is in the III quadrant.
We can write similar steps and obtain the same result.

(iv) In fig.14.5(d) above, M is in the IV quadrant.
We can write similar steps and obtain the same result.

• So whichever be the quadrant, the horizontal displacement of the magenta sphere will be $\small{A\,\cos \theta}$ 

5. We see that, this method is very effective to write the horizontal displacement of the magenta sphere. But we want the horizontal displacement of the red block.
• So we assume that:
   ♦ At the instant when the block is released from P, the sphere starts the revolution from P
   ♦ At the instant when the block reaches O, the sphere reaches R
   ♦ At the instant when the block reaches Q, the sphere also reaches Q
   ♦ At the instant when the block returns through O, the sphere reaches S
   ♦ At the instant when the block returns back at P, the sphere also reaches back at P

6. That means, the time period (T) for one oscillation of the block is same as the time for one revolution of the sphere. Using this information, we can write an expression for $\small{\theta}$
• Time for one revolution of the sphere = T seconds
⇒ Time for $\small{2 \pi}$ radians = T seconds
⇒ Time for 1 radian = $\small{\frac{T}{2 \pi}}$ seconds
⇒ Angular distance covered in 1 second  = $\small{\frac{2 \pi}{T}}$ radian
• The stop-watch is turned on at the instant when the block is released from P. At that same instant, the sphere starts the revolution from the same point P.
• Consider the instant at which the reading in the stop-watch is t. Let at that instant, the sphere be at M.
• So when the reading is t, the angular distance covered is $\small{\theta}$
• Angular distance covered in 1 second  = $\small{\frac{2 \pi}{T}}$ radian
⇒ Angular distance covered in t seconds  = $\small{\frac{2 \pi t}{T}}$ radian
⇒ $\small{\theta}$  = $\small{\frac{2 \pi t}{T}}$ radian
• So we can write:
At any time t,
The horizontal displacement of the sphere from O
= The horizontal displacement of the block from O
= $\small{A\,\cos\theta~=~A\,\cos\left(\frac{2 \pi t}{T} \right)}$
• That means:
$\small{x(t)~=~A\,\cos\left(\frac{2 \pi t}{T} \right)}$

7. We derived the equation: $\small{x(t)~=~A\,\cos\theta~=~A\,\cos\left(\frac{2 \pi t}{T} \right)}$.
• If we want, we can use $\small{\omega}$ instead of $\small{T}$.
• We have:
the angle subtended by the sphere, at O, in each second, is $\small{\omega}$.
• So in $\small{t}$ seconds, the sphere will subtend $\small{\omega\,t}$ radians at O
• But the angle subtended by the sphere, at O, in $\small{t}$ seconds, is $\small{\theta}$.
• That means: $\small{\theta~=~\omega\,t}$
• Thus we get:
$\small{x(t)~=~A\,\cos\theta~=~A\,\cos\left(\frac{2 \pi t}{T} \right)~=~A\,\cos\left(\omega\,t \right)}$.

8. Here, the only variable on the R.H.S is $\small{t}$.
   ♦ $\small{t}$ is the independent variable
   ♦ $\small{x}$ is the dependent variable
• So while drawing the graph, we must plot $\small{t}$ along the x-axis and $\small{x}$ along the y-axis.

9. One such graph is shown in fig.14.6 below.
   ♦ A is assumed to be 2.5 units
   ♦ T is assumed to be 6 s

Fig.14.6

• We get:
$\small{x(t)~=~A\,\cos\left(\frac{2 \pi t}{T} \right)~=~(2.5)\,\cos\left(\frac{2 \pi t}{6} \right)~=~(2.5)\,\cos\left(\frac{\pi t}{3} \right)}$

• Let us write some of the information that can be obtained from the graph:
(i) To find the instants at which the red block reaches the positive extreme, we need to solve the equation:
$\small{x(t)~=~2.5~=~(2.5)\,\cos\left(\frac{\pi t}{3} \right)}$
$\small{\Rightarrow 1~=~\cos\left(\frac{\pi t}{3} \right)}$

• This is a trigonometrical equation. We have seen the method to solve such equations, in our math classes (Details here).
• We get: t = 0, 6, 12, . . .
• The points are marked on the graph. Indeed we see that, the y-coordinates at these points are all 2.5

(ii) To find the instants at which the red block reaches the negative extreme, we need to solve the equation:
$\small{x(t)~=~-2.5~=~(2.5)\,\cos\left(\frac{\pi t}{3} \right)}$
$\small{\Rightarrow -1~=~\cos\left(\frac{\pi t}{3} \right)}$

• This is a trigonometrical equation. Solving it, we get:
t = 3, 9, 6, . . .
• The points are marked on the graph. Indeed we see that, the y-coordinates at these points are all −2.5

(iii) To find the instants at which the red block reaches the equilibrium position, we need to solve the equation:
$\small{x(t)~=~0~=~(2.5)\,\cos\left(\frac{\pi t}{3} \right)}$
$\small{\Rightarrow 0~=~\cos\left(\frac{\pi t}{3} \right)}$

• This is a trigonometrical equation. Solving it, we get:
t = 1.5, 4.5, 7.5, 10.5, . . .
• The points are marked on the graph. Indeed we see that, the y-coordinates at these points are all zero.


Phase constant

This can be explained in steps:
1. Consider fig.14.4 again. We turned the stop-watch on, when the red sphere was at P. Then we noted the time 't' at which the red sphere is at the arbitrary point M. The angle MOP at time 't' is denoted as '$\small{\theta}$'

2. The same fig.14.4 is modified and shown again in fig.14.7 below:

Fig.14.7

• Here, the stop-watch is turned on, when the sphere is at B. At B, the line OB already makes an angle $\small{\phi}$ with the x-axis.
• So at time 't', the sphere is at the arbitrary point M and the line OM makes an angle of $\small{\theta + \phi}$ with the x-axis
• Therefore in this case, the horizontal displacement of the sphere from O, at time 't' is given by:
$\small{x(t)~=~A \,\cos\left(\theta + \phi \right)}$

3. Let us draw the graph. It is shown in fig.14.8 below. For easy comparison, the previous graph in red color, is also shown as such. The new graph is shown in green color. For the new graph:
   ♦ A is the same 2.5 units
   ♦ T is the same 6 s
   ♦ $\small{\phi}$ is assumed to be $\small{\frac{\pi}{6}}$

Fig.14.8

• We get:
$\small{x(t)~=~A\,\cos\left(\frac{2 \pi t}{T}+\phi \right)~=~(2.5)\,\cos\left(\frac{2 \pi t}{6}+\frac{\pi}{6} \right)~=~(2.5)\,\cos\left(\frac{\pi t}{3}+\frac{\pi}{6} \right)}$

• Let us write some of the information that can be obtained from the graph:
(i) To find the instants at which the red block reaches the positive extreme, we need to solve the equation:
$\small{x(t)~=~2.5~=~(2.5)\,\cos\left(\frac{\pi t}{3}+\frac{\pi}{6} \right)}$
$\small{\Rightarrow 1~=~\cos\left(\frac{\pi t}{3}+\frac{\pi}{6} \right)}$

• This is a trigonometrical equation. Solving it, we get:
t = 5.5, 11.5, . . .
• The points are marked on the graph. Indeed we see that, the y-coordinates at these points are all 2.5

(ii) To find the instants at which the red block reaches the negative extreme, we need to solve the equation:
$\small{x(t)~=~-2.5~=~(2.5)\,\cos\left(\frac{\pi t}{3}+\frac{\pi}{6} \right)}$
$\small{\Rightarrow -1~=~\cos\left(\frac{\pi t}{3}+\frac{\pi}{6} \right)}$

• This is a trigonometrical equation. Solving it, we get:
t = 2.5, 8.5, . . .
• The points are marked on the graph. Indeed we see that, the y-coordinates at these points are all −2.5

(iii) To find the instants at which the red block reaches the equilibrium point, we need to solve the equation:
$\small{x(t)~=~0~=~(2.5)\,\cos\left(\frac{\pi t}{3}+\frac{\pi}{6} \right)}$
$\small{\Rightarrow 0~=~\cos\left(\frac{\pi t}{3}+\frac{\pi}{6} \right)}$

• This is a trigonometrical equation. Solving it, we get:
t = 1, 4, 7, 10, . . .
• The points are marked on the graph. Indeed we see that, the y-coordinates at these points are all zero.

(iv) The green curve is an exact replica of the red curve. But the green is shifted by a small amount  towards the left.
• That means:
The green reaches the extreme points and zero points earlier than the red.
• For example:
   ♦ Red reaches a maximum at t = 6 s. Green reaches a maximum at t = 5.5 s
   ♦ Red reaches a minimum at t = 3 s. Green reaches a minimum at t = 2.5 s
   ♦ Red reaches a zero at t = 7.5 s. Green reaches a maximum at t = 7 s
• We say that:
The two oscillations are out of phase by an angle of $\small{\frac{\pi}{6}}$ radians
• The angle $\small{\phi~=~\frac{\pi}{6}}$
• $\small{\phi}$ is called the phase constant.


In the next section, we will see the oscillation of the same spring in the vertical direction.

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Saturday, January 24, 2026

Chapter 14 - Oscillations

In the previous section, we saw specific heats of gases. In this chapter, we will see oscillations.

• In some earlier chapters, we have seen rectilinear motion, projectile motion and uniform circular motion.
• In uniform circular motion, a particle takes the same time to complete each revolution. So it is a periodic motion.
• In this chapter, we will see another type of periodic motion, called oscillation.
• In oscillation, a particle moves to and fro about a mean position.
   ♦ Motion of the pendulum is an example
   ♦ Motion of the piston inside the cylinder of an engine is another example.   
• To learn about periodic motion and oscillatory motion, we must first see some fundamental concepts like period, frequency, displacement etc., They are explained below:

Periodic and Oscillatory motions

Some basics can be written in 5 steps:
1. Consider an insect climbing up a wall. It starts climbing from the ground level. It travels with a uniform speed u1. In a time duration of t1, it reaches a height h. This is shown by the red line in fig.14.1(a) below:

Fig.14.1

• After t1, the insect is not able to climb upwards. Neither is it able to hold on. So it climbs down to the ground with a uniform speed of u2.  The time taken for reaching the ground is t2. This is shown by the green line in fig.14.1(a) above.
• Note that, t1 is larger than t2. This is because, time taken to reach the ground is smaller.
• The sum (t1 + t2) is T. This T is the time required to start from  the ground and reach back to the ground. If the insect keep repeating the "climbing and falling" process, we will get several repetitions in the graph. The ground is then considered as the mean position.
• The red line is familiar to us. We have plotted many distance-time (s-t) graphs in rectilinear motion. If the motion is uniform, we get the same red line. It is the plot of the equation s = ut. In our present case, u1 is the slope of the red line. u1 is constant.
• The green line can also be given a similar explanation. It has a negative slope because, velocity is negative for downward motion. So slope of the green line is −u2.
• In fig.14.1, instead of s, we plot x(t) along the y-axis. This is because, in periodic motion, the displacement from the mean position is denoted by x. It is a function of time. So we write x(t).

2. Consider the game of bouncing the ball between palm and ground.
• The game starts when the ball is thrown to the ground from a height h. It is thrown with an initial speed of u1. Since the ball is under the influence of gravity, speed is not uniform.
• The displacement at any instant 't' is given by:
$\small{x(t)\,=\,u_1 t + \frac{1}{2} a t^2}$. This is the equation of a parabola.
• In a time duration of t1, it reaches the ground. This is shown by the red parabola in fig.14.1(b) above.
• After t1, the ball bounces upwards with a speed of u2. Since the ball is under the influence of gravity, speed is not uniform. The displacement at any instant 't' is given by:
$\small{x(t)\,=\,u_2 t - \frac{1}{2} a t^2}$. This is the equation of a parabola.
• In a time duration of t2, it reaches the palm. This is shown by the  green parabola in fig.14.1(b) above.
• The sum (t1 + t2) is T. This T is the time required to start from  the palm and reach back to the palm. As the game continues, we will get several repetitions in the graph. The ground is then considered as the mean position.
• Note that, the red and green parabolas are graphs. They are not the paths followed by the ball. The path of the ball is always vertical. While playing this game, the ball cannot be thrown in a parabolic path. If the ball is thrown in a parabolic path, it will not bounce back to the palm. It will bounce away from the player.

3. A motion that repeats itself at regular intervals of time is called a periodic motion.

4. Consider the red sphere in fig.14.2 below. It is at the bottom of the yellow bowl.

Fig.14.2

• In this position, the sphere is at equilibrium. If the sphere is left alone, it will remain there forever.
• But if the sphere is given a displacement, a force will come into play, which tries to bring the sphere back to the equilibrium position. As a result, the sphere will perform oscillation or vibration in the bowl.
• Oscillating bodies eventually come to rest. In our present case, the sphere will come to rest at the bottom of the bowl.
• This is due to the friction between the sphere and the bowl. The surrounding air also causes the sphere to come to rest. This type of oscillation is called damped oscillation.
• However, an oscillation can be forced to remain oscillating, by providing an external agency. This type of oscillation is called forced oscillation. We will see the details of both types in later sections of this chapter.

5. Every oscillatory motion is a periodic motion.
• But every periodic motion need not be an oscillatory motion.
   ♦ Circular motion is periodic but not oscillatory.

Period and frequency

This can be explained in 7 steps:
1. Consider the earlier fig.14.1(a). We turn on the stop-watch at the instant when the insect begins to climb up. When the reading in the stop-watch is T, the insect is back on the ground, and the next cycle begins.

2. In fig.14.1(b), we turn on the stop-watch at the instant when the ball is thrown. When the reading in the stop-watch is T, the ball is back at the palm, and the next cycle begins.

3. So we can write:
The smallest duration of time after which the next cycle begins, is called the period of the periodic motion. It is denoted by the symbol T.
• The S.I unit of period is second.

4. For periodic motions which are too fast, period will be very small. In such cases, instead of s, we can use other units.
• For example, the period of vibration of a quartz crystal is expressed in microseconds.
   ♦ One microsecond is $\small{10^{-6}}$ seconds.
   ♦ Microsecond is abbreviated as: $\small{{\rm{\mu s}}}$

5. For periodic motions which are too slow, period will be very large. In such cases also, instead of s, we can use other units.
• For example, the orbital period of some  planets are expressed in earth days.
   ♦ For mercury, it is 88 earth days.
   ♦ One earth day is 24 hours.

6. Suppose that, period of a periodic motion is 30 s. Then in one minute, two cycles will occur.
   ♦ That is., in 60 s, two cycles will occur
   ♦ That is., in 1 s, 2/60 cycles will occur.
   ♦ That is., in 1 s, 1/30 cycles will occur.
   ♦ That is., in 1 s, 1/30 of one cycle will occur.
• The number of cycles in one second is called frequency. It is represented by the symbol $\small{\nu}$. In our present case, $\small{\nu}$ = 1/30.
• Note that, 1/30 is the reciprocal of 30. And 30 is the period in seconds.
• So we can write:
Frequency is the reciprocal of period. The period must be in seconds.
   ♦ That is., $\small{\nu~=~\frac{1}{T}}$
   ♦ where T is n seconds.
• Since we are taking the reciprocal of "period in seconds", the unit of frequency is $\small{{\rm{s^{-1}}}}$.
This $\small{{\rm{s^{-1}}}}$ is given a special name. It is called hertz (abbreviated as Hz), in honor of the scientist Heinrich Rudolph Hertz, who discovered radio waves.
• We can write:
1 hertz = 1 Hz = 1 cycle per second = 1 $\small{{\rm{s^{-1}}}}$.

7. Note that, $\small{\nu}$ need not be an integer. It can be a decimal or a fraction.

Let us see a solved example:

Solved example 14.1
On an average, a human heart is found to beat 75 times in a minute. Calculate it's frequency and period.
Solution
:
1. First, let us calculate the frequency:
Number of occurrences in one minute = 75
⇒ Number of occurrences in 60 s = 75
⇒ Number of occurrences in 1 s = 75/60
⇒ Frequency $\small{\nu~=~\frac{75}{60}~=~\frac{5}{4}~=~1.25~{\rm{s^{-1}}}}$
2. Now we can calculate the period:
We know that, frequency is the reciprocal of period. It follows that, period is the reciprocal of frequency. So we can write:
Period $\small{T~=~\frac{1}{\nu}~=~\frac{4}{5}~=~0.8 {\rm{s}}}$


In the next section, we will see displacement.

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Monday, January 19, 2026

13.4 - Specific Heat Capacity of Solids

In the previous section, we saw specific heats of gases. In this section, we will see specific heat capacity of solids.

Details can be written in 4 steps:

1. For a solid atom, there will not be any translation or rotation. There will be vibration only.
• So by applying law of equipartition, We know that:
For each atom at temperature T, this energy will be $\small{K_B\,T}$
• Due to the vibration in all three dimensions, the average energy will be $\small{3K_B\,T}$.

2. In a mole of the solid, there will be $\small{N_A}$ atoms. So the total internal energy (U) of one mole of a solid can be obtained as:
$\small{U\,=\,3 K_B\,T\,N_A\,=\,3 R\,T}$

3. At constant pressure, we know that:
$\small{\Delta Q\,=\,\Delta U\,+\,P \Delta V}$ 
• For a solid, $\small{\Delta V}$ is negligible. So we get:
$\small{\Delta Q\,=\,\Delta U}$   

4. Specific heat is the change in internal energy per unit change in temperature. So we can obtain the specific heat for one mole as:
$\small{C\,=\,\frac{3 R\,T}{T}\,=\,3 R}$


Using the above equation, we can predict the specific heat of different solids. At ordinary temperature, the predicted values are in agreement with the experimental values. However, carbon is an exception. We will see the reason in higher classes.


Specific heat capacity of water

Details can be written in 4 steps:
1. We treat water like a solid. We saw that, for each solid atom, the energy is $\small{3K_B\,T}$. For each water molecule there are three atoms. So for a water molecule, the energy is $\small{9K_B\,T}$.

2. In a mole of the water, there will be $\small{N_A}$ molecules. So the total internal energy (U) of one mole of water can be obtained as:
$\small{U\,=\,9 K_B\,T\,N_A\,=\,9 R\,T}$

3. At constant pressure, we know that:
$\small{\Delta Q\,=\,\Delta U\,+\,P \Delta V}$ 
• Since we treat water as a solid, $\small{\Delta V}$ is negligible. So we get:
$\small{\Delta Q\,=\,\Delta U}$   

4. Specific heat is the change in internal energy per unit change in temperature. So we can obtain the specific heat for one mole as:
$\small{C\,=\,\frac{9 R\,T}{T}\,=\,9 R}$


Using the above equation, we can predict the specific heat of water. The predicted value is in agreement with the experimental value.

• If we use the use the unit “$\small{\text{calorie}\, \text{gram}^{-1} \,\text{K}^{-1} }$”, the specific heat of water is one.
• Let us convert the unit into “$\small{\text{J}\, \text{mol}^{-1} \,\text{K}^{-1} }$”
    ♦ One calorie is 4.179 joules
    ♦ One mole of water is 18 grams.
• So we get:
$\small{1~\text{calorie}\, \text{gram}^{-1} \,\text{K}^{-1}~=~\frac{1(4.179)}{(1/18)}~=~75.222~\text{joule}\, \text{mole}^{-1} \,\text{K}^{-1} }$
• Now, 9R = 9(8.31) = 74.79 $\small{\text{joule}\, \text{mole}^{-1} \,\text{K}^{-1} }$
• So the values are in agreement.


Next we will see an important aspect about the predicted values. It can be written in 4 steps:

1. We have seen the formulas for calculating the specific heats of various substances. In those formulas, temperature is absent. That means, the predicted values are calculated without taking temperature into account.

2. The experimental values have a marked difference from predicted values, when temperature is low. When experiments are done at temperatures close to zero, the specific heats also approach zero.
• This is because, when a substance freeze, the molecules/atoms in it have nearly zero degrees of freedom.

3. The kinetic theory is based on classical physics. For applying classical physics, the degrees of freedom must remain unchanged at all times.

4. However, quantum mechanics can make more accurate predictions. We will see those details in higher classes.


Mean free path

• Molecules in a gas are moving with large speeds. Speeds that are comparable to the speed of sound. But consider the case when cooking gas leaks from a faulty cylinder. The person at the other side of the room will become aware of the leakage, only after a short duration of time. That means, the molecules of the gas did not travel at the speed of sound, all the way to the other side of the room.
• Similar is the case of a cloud of smoke. The top of the cloud retains the shape for a considerable duration of time. If the molecules of the smoke travel at the speed of sound, in imaginary straight lines drawn in all directions, we will be seeing instant dispersal of the smoke.
• Scientists have discovered the reason for such behaviour. They found out that, the molecules of the gas/smoke undergo collisions. Due to the collisions, the molecules cannot move in straight lines. The direction changes continuously.

Let us try to make a mathematical model for the ‘possibility for collision’. It can be written in 12 steps:
1. Suppose that, the molecules of a gas are spheres of diameter d. Let us concentrate on one such sphere.
• It is the middle sphere in fig.13.3 (a) below. Let it be traveling with the average speed $\small{\bar{v}}$.

Fig.13.3

2. Consider any near by sphere. If the distance between the centers of the two spheres is less than or equal to ‘d’, then there is a possibility for collision.
• In the fig.13.3 above, the middle sphere can collide with any other sphere,
   ♦ whose edge is on the green dashed line   
   ♦ whose edge is between blue and green dashed lines   
   ♦ whose edge is on the red dashed line   
   ♦ whose edge is between blue and red dashed lines   

3. So we can think about a cylinder whose radius is ‘d’. This cylinder is shown in yellow color in the fig.13.3 above. Note that:
   ♦ Diameter of the spheres is ‘d’
   ♦ Radius of the cylinder is also ‘d’
         ✰ This is shown in the diagram shown in fig.13.3(b).
• Then base area of the cylinder will be: $\small{\pi d^2}$

4. Height of the cylinder is equal to the distance traveled by the middle sphere in time $\small{\Delta t}$, which is equal to $\small{\bar{v}\,\Delta t}$
• So volume of the cylinder will be $\small{\pi d^2\,\bar{v}\,\Delta t}$

5. All spheres whose center is on or within the edge of the cylinder, will have a possibility for collision with the middle sphere.

6. If n is the number of spheres per unit volume, then the number of spheres mentioned in (5) will be, n times the volume of the cylinder, which gives: $\small{n\pi d^2\,\bar{v}\,\Delta t}$
• That means, the number of collisions in the time duration of $\small{\Delta t}$ is $\small{n\pi d^2\,\bar{v}\,\Delta t}$

7. So the number of collisions in one second will be: $\small{\Delta t}$ is $\small{n\pi d^2\,\bar{v}}$

8. Let $\small{\tau}$ be the average time between two successive collisions. Then we can write:
$\small{\tau}$  × Number of collisions in one second = one second
Therefore, $\small{\tau~=~\frac{1}{n\pi d^2\,\bar{v}}}$

9. This average time, multiplied by the average speed will give the average distance between two successive collisions. 
• The average distance between two successive collisions is called mean free path ($\small{l}$).
• So we can write:
$\small{l\,=\,\tau\,\bar{v}\,=\,\frac{\bar{v}}{n\pi d^2\,\bar{v}}}$
$\small{\Rightarrow l\,=\,\frac{1}{n\pi d^2}}$  

10. Let us do a dimensional analysis of the equation derived in (9) above.
   ♦ The dimension of $\small{l}$ is $\small{L}$ 
   ♦ 'n' is number per volume. So it's dimensions are: $\small{L^{-3}}$
   ♦ The dimensions of $\small{d^2}$ is $\small{L^2}$ 
So the dimensions of R.H.S is: $\small{\frac{1}{L^{-3}L^2}~=~L}$

11. We derived the equation in (9) by considering the motion of the middle sphere in fig.13.3 above. We assumed that, all other spheres (molecules) are at rest. But in reality, all molecules are in motion.

• So instead of $\small{\bar{v}}$, we need to use $\small{\bar{v}_r}$, which is the average relative velocity.
• Based on this modification, scientists have derived a more accurate equation: $\small{l\,=\,\frac{1}{\sqrt{2}\,n\pi d^2}}$

12. Let us see an example:
We are given one mole of air molecules at STP. We want to find $\small{\tau}$ and the mean free path.
This can be done in steps:
(i) One mole of air molecules is $\small{6.02 ~\times~10^{23}}$ molecules. At STP, this number of molecules will occupy $\small{22.4~\times~10^{-3}~{\rm{m^3}}}$

(ii) So the number of molecules (n) in one cubic meter, can be calculated as:
$\small{n~=~\frac{6.02 ~\times~10^{23}}{22.4~\times~10^{-3}~{\rm{m^3}}}~=~2.7~\times~10^{25}~{\rm{m^{-3}}}}$

(iii) Let
   ♦ d, the diameter of an air molecule = $\small{2~\times~10^{-10}~{\rm{m}}}$
   ♦ $\small{\bar{v}}$, the average velocity of an air molecule = $\small{485~{\rm{m\,s^{-1}}}}$

(iv) Then from the equation in (8), we get:
$\small{\tau~=~\frac{1}{(2.7~\times~10^{25}~{\rm{m^{-3}}})\pi (2~\times~10^{-10}~{\rm{m}})^2\,(485~{\rm{m\,s^{-1}}} )}~=~6.1~\times~10^{-10}~{\rm{s}}}$

(v) Also, from the equation in (9), we get:
$\small{l\,=\,\tau\,\bar{v}\,=\,6.1~\times~10^{-10}~{\rm{s}}~\times~485~{\rm{m\,s^{-1}}}~=~2.9~\times~10^{-7}~{\rm{m}}}$

(vi) $\small{2.9~\times~10^{-7}~{\rm{m}}}$ is approximately equal to 1500d
• That means, the air molecule is able to travel 1500 times it's diameter between two successive collisions.


In the next chapter, we will see oscillations.

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Thursday, January 15, 2026

13.3 - Specific Heats of Gases

In the previous section, we saw the law of equipartition of energy. In this section, we will apply the law to predict the specific heats of gases.

First we will see monatomic gases. The details can be written in 5 steps:

1. For a monatomic gas molecule, there will not be any rotation or vibration. So we need to consider the translational kinetic energy only.
• Applying law of equipartition, We get:
For each molecule at temperature T, this energy will be $\small{\frac{3}{2}K_B\,T}$

2. In a mole of the gas, there will be $\small{N_A}$ molecules. So the total internal energy (U) of one mole of a monatomic gas can be obtained as:
$\small{U\,=\,\frac{3}{2}K_B\,T\,N_A\,=\,\frac{3}{2}R\,T}$  

3. Specific heat is the change in internal energy per unit change in temperature. So we can obtain the specific heat for one mole at constant volume as:
$\small{C_v\,\text{monatomic gas}\,=\,\frac{3}{2}R}$

4. For an ideal gas, $\small{C_p\,-\,C_v\,=\,R}$
Where $\small{C_p}$ is the specific heat for one mole at constant pressure. We can write:
$\small{C_p\,=\,R\,+\,C_v\,=\,\frac{5}{2}R}$

5. We can write the ratio of specific heats also:
$\small{\gamma\,=\,\frac{C_p}{C_v}\,=\,\frac{5}{3}}$


Next we will see diatomic gases whose molecules are rigid. The details can be written in 5 steps:

1. For a diatomic gas molecule, assuming that it is rigid, there will not be any vibration. So we need to consider the translational and rotational kinetic energies only.
• Applying law of equipartition, We get:
For each molecule at temperature T, this energy will be $\small{5\times \frac{1}{2}K_B\,T~=~\frac{5}{2}K_B\,T}$

2. In a mole of the gas, there will be $\small{N_A}$ molecules. So the total internal energy (U) of one mole of a diatomic gas can be obtained as:
$\small{U\,=\,\frac{5}{2}K_B\,T\,N_A\,=\,\frac{5}{2}R\,T}$  

3. Specific heat is the change in internal energy per unit change in temperature. So we can obtain the specific heat for one mole at constant volume as:
$\small{C_v\,\text{rigid diatomic gas}\,=\,\frac{5}{2}R}$

4. For an ideal gas, $\small{C_p\,-\,C_v\,=\,R}$
Where $\small{C_p}$ is the specific heat for one mole at constant pressure. We can write:
$\small{C_p\,=\,R\,+\,C_v\,=\,\frac{7}{2}R}$

5. We can write the ratio of specific heats also:
$\small{\gamma\,=\,\frac{C_p}{C_v}\,=\,\frac{7}{5}}$


Next we will see diatomic gases whose molecules are not rigid. The details can be written in 5 steps:

1. For a diatomic gas molecule, if it is not rigid, there will be vibration.
• Applying law of equipartition, We get:
For each molecule at temperature T, this energy will be $\small{5\times \frac{1}{2}K_B\,T\,+\,K_B\,T~=~\frac{7}{2}K_B\,T}$

2. In a mole of the gas, there will be $\small{N_A}$ molecules. So the total internal energy (U) of one mole of a diatomic gas can be obtained as:
$\small{U\,=\,\frac{7}{2}K_B\,T\,N_A\,=\,\frac{7}{2}R\,T}$  

3. Specific heat is the change in internal energy per unit change in temperature. So we can obtain the specific heat for one mole at constant volume as:
$\small{C_v\,\text{non-rigid diatomic gas}\,=\,\frac{7}{2}R}$

4. For an ideal gas, $\small{C_p\,-\,C_v\,=\,R}$
• We can write:
$\small{C_p\,=\,R\,+\,C_v\,=\,\frac{9}{2}R}$

5. We can write the ratio of specific heats also:
$\small{\gamma\,=\,\frac{C_p}{C_v}\,=\,\frac{9}{5}}$


Next we will see polyatomic gases. The details can be written in 5 steps:

1. In general, a polyatomic molecule has:
    ♦ 3 translational degrees of freedom
    ♦ 3 rotational degrees of freedom
    ♦ $\small{f}$ number of vibrational modes

• Applying law of equipartition, We get:
For each molecule at temperature T, this energy will be $\small{3\times \frac{1}{2}K_B\,T\,+\,3\times \frac{1}{2}K_B\,T\,+f\,\,K_B\,T~=~(3+f)K_B\,T}$

2. In a mole of the gas, there will be $\small{N_A}$ molecules. So the total internal energy (U) of one mole of a polyatomic gas can be obtained as:
$\small{U\,=\,(3+f)K_B\,T\,N_A\,=\,(3+f)R\,T}$  

3. Specific heat is the change in internal energy per unit change in temperature. So we can obtain the specific heat for one mole at constant volume as:
$\small{C_v\,\text{polyatomic gas}\,=\,(3+f)R}$

4. For an ideal gas, $\small{C_p\,-\,C_v\,=\,R}$
• We can write:
$\small{C_p\,=\,R\,+\,C_v\,=\,(4+f)R}$

5. We can write the ratio of specific heats also:
$\small{\gamma\,=\,\frac{C_p}{C_v}\,=\,\frac{4+f}{3+f}}$


Using the above equations, we can predict the specific heats of different types of gases. Two examples are given below. In those examples, vibrational modes are ignored:

Example 1:
• Predicted value of $\small{C_v}$ and $\small{C_p}$ for monatomic gas are 12.5 J mol−1 K−1 and 20.8 J mol−1 K−1 respectively.
• Experimental value of $\small{C_v}$ and $\small{C_p}$ for the monatomic gas helium are 12.5 J mol−1 K−1 and 20.8 J mol−1 K−1 respectively.

Example 2:
• Predicted value of $\small{C_v}$ and $\small{C_p}$ for diatomic gas are 20.8 J mol−1 K−1 and 29.1 J mol−1 K−1 respectively.
• Experimental value of $\small{C_v}$ and $\small{C_p}$ for the diatomic gas oxygen are 21.0 J mol−1 K−1 and 29.3 J mol−1 K−1 respectively.

If vibrational modes are included in the calculations, the predicted values become closer to the experimental values.

Now we will see some solved examples.

Solved example 13.14
A cylinder of fixed capacity 44.8 litres contains helium gas at standard temperature and pressure. What is the amount of heat needed to raise the temperature of the gas in the cylinder by 15.0 °C ? (R = 8.31 J mol−1 K−1)
Solution
:
1. Helium is a monatomic gas.
• So $\small{C_v\,=\,\frac{3}{2} R}$ and $\small{C_p\,=\,\frac{5}{2} R}$
• Given that, cylinder is of fixed capacity. That means, volume is constant. So we have to use $\small{C_v}$.

2. Heat required
= $\small{C_v~\times~\text{no. of moles}~\times~\text{rise in temperature}}$

3. So our next task is to find the number of moles of helium present in the cylinder.
• Given that, the gas is at STP. We know that, at STP, one mole of an ideal gas will have a volume of 22.4 litres.
• In our present case, the volume is 44.8 litres. So there are two moles.

4. Thus from (2), we get:
Heat required
= $\small{\frac{3}{2} R~\times~2~\times~15}$

= $\small{\frac{3}{2} \left(8.31 \text{J}\, \text{mol}^{-1} \,\text{K}^{-1} \right)~\times~2(\text{mol})~\times~15\left(\text{K} \right)}$

= $\small{373.95 \,\text{J}}$


In the next section, we will see specific heat capacity of solids.

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Tuesday, January 13, 2026

13.2 - Law of Equipartition of Energy

In the previous section, we explained the gas laws using kinetic theory. In this section, we will see the law of equipartition of energy.

The details can be written in 17 steps:
1. Consider a gas in thermal equilibrium at temperature T.
If 'm' is the mass of each molecule in that gas, then the average value of energy ($\small{\epsilon_t}$) of each molecule can be obtained as:
$\small{\epsilon_t~=~\frac{1}{2}m\,v_x^2~+~\frac{1}{2}m\,v_y^2~+~\frac{1}{2}m\,v_z^2~=~\frac{3}{2}K_B\,T}$

2. $\small{\frac{3}{2}K_B\,T}$ is three times $\small{\frac{1}{2}K_B\,T}$. We know that, there is no preferred direction. So we can write:
    ♦ $\small{\frac{1}{2}m\,v_x^2~=~\frac{1}{2}K_B\,T}$
    ♦ $\small{\frac{1}{2}m\,v_y^2~=~\frac{1}{2}K_B\,T}$
    ♦ $\small{\frac{1}{2}m\,v_z^2~=~\frac{1}{2}K_B\,T}$

3. Now we will write about the number of coordinates required for a molecule.
• If the molecule is free to move in space, we need three coordinates to locate it.
• If the molecule is constrained to move in a plane, we need two coordinates to locate it.
• If the molecule is constrained to move along a line, we need only one coordinate to locate it.

4. The above information in (3) can be written in another form also:
• If the molecule is free to move in space, it has three degrees of freedom.
• If the molecule is constrained to move in a plane, it has two degrees of freedom.
• If the molecule is constrained to move along a line, it has one degree of freedom.

5. The above information in (3) and (4) can be written in yet another form also. Motion of a body as a whole from one point to another is called translation. So we can write:
• If the molecule is free to move in space, it has three translational degrees of freedom.
• If the molecule is constrained to move in a plane, it has two translational degrees of freedom.
• If the molecule is constrained to move along a line, it has one translational degree of freedom.

6. We just saw that, if a molecule is free to move in space, it has three translational degrees of freedom. Each of those three degrees, will contribute a term towards the total kinetic energy of the molecule.
• The degree of freedom in the x-direction will contribute $\small{\frac{1}{2}m\,v_x^2}$
• The degree of freedom in the y-direction will contribute $\small{\frac{1}{2}m\,v_y^2}$
• The degree of freedom in the z-direction will contribute $\small{\frac{1}{2}m\,v_z^2}$

7. Consider a diatomic gas like oxygen ($\small{O_2}$) or nitrogen ($\small{N_2}$). Each molecule of such a gas will have two atoms.
• In fig.13.2 below, the brown spheres represent atoms.
• Two brown spheres are joined together by a yellow line. • This line represents the bond between the two atoms.
    ♦ The green line is perpendicular to the yellow line.
    ♦ The red line is also perpendicular to the yellow line.
    ♦ The green and red lines are perpendicular to each other.

Fig.13.2

8. In the fig. on the left side, the molecule as a whole, is rotating about the green line. So green line is the axis of rotation. It is marked as (1).
• Due to this rotation, the molecule will have a rotational energy equal to $\small{\frac{1}{2}\,I_1\,\omega_1^2}$
    ♦ $\small{I_1}$ is the moment of inertia of the molecule about axis (1)
    ♦ $\small{\omega_1}$ is the angular speed of the molecule about axis (1)

9. In the fig. on the right side, the molecule as a whole, is rotating about the red line. So red line is the axis of rotation. It is marked as (2).
• Due to this rotation, the molecule will have a rotational energy equal to $\small{\frac{1}{2}\,I_2\,\omega_2^2}$
    ♦ $\small{I_2}$ is the moment of inertia of the molecule about axis (2)
    ♦ $\small{\omega_2}$ is the angular speed of the molecule about axis (2)

10. The molecule can rotate about the yellow line also. But the moment of inertia of the molecule about the yellow line is very small. So this rotation will not contribute much to the total rotational energy. We can safely ignore this rotation.

11. Based on (8) and (9), we can write:
Rotational energy of the molecule is given by:
$\small{\epsilon_r~=~\frac{1}{2}\,I_1\,\omega_1^2~+~\frac{1}{2}\,I_2\,\omega_2^2}$

• It is clear that, a diatomic molecule has two rotational degrees of freedom.
    ♦ One along axis (1)
    ♦ The other along axis (2)

12. So a diatomic molecule has a total energy given by:
$\small{\epsilon_t\,+\,\epsilon_r\,=\,\frac{1}{2}m\,v_x^2\,+\,\frac{1}{2}m\,v_y^2\,+\,\frac{1}{2}m\,v_z^2\,+\,\frac{1}{2}\,I_1\,\omega_1^2\,+\,\frac{1}{2}\,I_2\,\omega_2^2}$

• Note that, for a monatomic molecule, the last two terms will be absent.

13. We have seen the energy contributions from translation and rotation. If a molecule experience vibration, that molecule will posses vibrational energy also.
• Consider the two spheres in fig.13.2 above. If the spheres oscillate along the yellow line, then that molecule as a whole, will posses vibrational energy. It is like a spring with the two spheres at it's ends. We will see more details in later chapters.
• The $\small{O_2}$ molecule is rigid. So this energy does not come into effect at moderate temperatures. But a $\small{CO}$ molecule will posses this energy even at moderate temperatures.

14. For a molecule like $\small{CO}$, the vibrational energy is given by:
$\small{\epsilon_v\,=\,\frac{1}{2} m \left(\frac{dy}{dt} \right)^2\,+\,\frac{1}{2} k y^2}$
    ♦ $\small{k}$ is the force constant of the oscillator
    ♦ $\small{y}$ is the vibrational co-ordinate

15. Now we can write the total energy:
$\small{\epsilon\,=\,\epsilon_t\,+\,\epsilon_r\,+\,\epsilon_v}$

• Where,

$\small{\epsilon_t\,=\,\frac{1}{2}m\,v_x^2\,+\,\frac{1}{2}m\,v_y^2\,+\,\frac{1}{2}m\,v_z^2}$

$\small{\epsilon_r\,=\,\frac{1}{2}\,I_1\,\omega_1^2\,+\,\frac{1}{2}\,I_2\,\omega_2^2}$

$\small{\epsilon_v\,=\,\frac{1}{2} m \left(\frac{dy}{dt} \right)^2\,+\,\frac{1}{2} k y^2}$

16. Now we can analyze the contribution from each type of energy.
(i) Each of the translational degree of freedom, contributes one square term.
(ii) Each of the rotational degree of freedom, contributes one square term.
(iii) Each vibrational frequency, contributes two square terms.

17. Now we can write about the general form of contribution:
• We have seen that, each square term in the translational energy is equal to $\small{\frac{1}{2}K_B\,T}$
• The Scottish physicist James Clerk Maxwell proved that, each square term has an average energy equal to $\small{\frac{1}{2}K_B\,T}$. This is known as the law of equipartition of energy.
• So we can write:
    ♦ Each translational degree of freedom contributes $\small{\frac{1}{2}K_B\,T}$ to the total energy.
    ♦ Each rotational degree of freedom contributes $\small{\frac{1}{2}K_B\,T}$ to the total energy.
    ♦ Each vibrational frequency contributes two times $\small{\frac{1}{2}K_B\,T}$ = $\small{K_B\,T}$ to the total energy.

• We will see the detailed proof of the law in higher classes.


In the next section, we will apply the law to predict specific heats of gases theoretically.

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